Reactions of triethylgermyllithium with N, N-dialkylated carboxamides

DA Bravo-Zhivotovskii, SD Pigarev…

Index: Bravo-Zhivotovskii, D. A.; Pigarev, S. D.; Kalikhman, I. D.; Vyazankina, O. A.; Vyazankin, N. S. Journal of Organometallic Chemistry, 1983 , vol. 248, # 1 p. 51 - 60

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Citation Number: 20

Abstract

Abstract The reactions of triethylgermyllithium with N, N-dialkylated carboxamides have been investigated. N, N-Dimethylacetamide, N, N-dimethylpivalamide, N, N- diethyltrifluoroacetamide and N, N-diethylbenzamide act on triethylgermyllithium, which is made from bis (triethylgermyl) mercury and lithium in hexane, to release the corresponding acyltriethylgermanes as the principal product. The regioselectivity of the present reactions ...