Synlett

Reduction of organic halides with tri-2-furanylgermane: Stoichiometric and catalytic reaction

T Nakamura, H Yorimitsu, H Shinokubo, K Oshima

文献索引：Nakamura, Tomoaki; Yorimitsu, Hideki; Shinokubo, Hiroshi; Oshima, Koichiro Synlett, 1999 , # 9 p. 1415 - 1416

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被引用次数: 29

摘要

Abstract: Triethylborane-induced radical reduction of organic halides with tri-2- furanylgermane provided the corresponding reduced compounds in good yields. Radical cyclization of b-haloalkyl allyl ether or 6-halo-1-alkene afforded five-membered products under the same reaction conditions. These reactions proceeded with NaBH4 in the presence of a catalytic amount of germanium hydride. Key words: tri-2-furanylgermane, ...