The Journal of Organic Chemistry

Dichlorocarbene from flash vacuum pyrolysis of trimethyl (trichloromethyl) silane. Possible observation of 1, 1-dichloro-3-phenylcarbonyl ylide

JF Gisch, JA Landgrebe

文献索引：Gisch, John F.; Landgrebe, John A. Journal of Organic Chemistry, 1985 , vol. 50, # 12 p. 2050 - 2054

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被引用次数: 15

摘要

Flash vacuum pyrolysis of trimethyl (trichloromethy1) silane 3 at 500-700" C was shown to be a simple and efficient method for the production of: CC12 in the gas phase. The copyrolysis of silane 3 and benzaldehyde (7) at 600" C led to l, l, l-trichloro-2-phenyl-2- (trimethylsiloxy) ethane (8), a 1: l adduct, in addition to bend chloride (15) and a- chlorophenylacetyl chloride (16), products thought to arise from 1, l-dichloro 3-phenyl ...