Journal of the American Chemical Society

The preparation and properties of (hydroxyorgano)-silanes and related compounds

JL Speier

文献索引：Speier Journal of the American Chemical Society, 1952 , vol. 74, p. 1003,1005

全文：HTML全文

被引用次数: 145

摘要

Certain halophenols were treated with chlorosilanes to form (ha1ophenoxy)-silanes. Silylphenoxysilanes were prepared in good yields from (ha1ophenoxy)-silanes, chlorosilanes and sodium or potassium metal. Hydrolysis of silylphenoxysilanes is described as leading to various silylphenols or, in some cases, complex cleavage products. Chlorohydrins were treated with chlorosilanes to form chloroalkoxysilanes, which reacted ...