Journal of the American Chemical Society

The preparation and properties of (hydroxyorgano)-silanes and related compounds

JL Speier

Index: Speier Journal of the American Chemical Society, 1952 , vol. 74, p. 1003,1005

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Citation Number: 145

Abstract

Certain halophenols were treated with chlorosilanes to form (ha1ophenoxy)-silanes. Silylphenoxysilanes were prepared in good yields from (ha1ophenoxy)-silanes, chlorosilanes and sodium or potassium metal. Hydrolysis of silylphenoxysilanes is described as leading to various silylphenols or, in some cases, complex cleavage products. Chlorohydrins were treated with chlorosilanes to form chloroalkoxysilanes, which reacted ...