Tetrahedron letters

Reaction of dicarbomethoxycarbene with quadricyclane

ML Tetef, M Jones

文献索引：Tetef, Merry L.; Jones, Maitland Jr. Tetrahedron Letters, 1984 , vol. 25, # 2 p. 161 - 164

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被引用次数: 3

摘要

Dicarbomethoxycarbene reacts with quadricyclane to give mainly 3,3-dicarbomethoxy- -tricyclo[3.2.1.0 2,4 ]oct-6-ene. Although this is the same major product as formed by reaction of the carbene with norbornadiene, it is shown that reaction with quadricyclane is direct and does not involve prior isomerization to the diene. ... Our results will be reported in detail in a forthcoming Tetrahedron Symposium in Print. ... Compounds 3 and 5 are known; 12 we synthesized ...