New syntheses of 1-chloroalkylphosphinates

X Morise, P Savignac, JM Denis

文献索引：Morise, Xavier; Savignac, Philippe; Denis, Jean-Marc Journal of the Chemical Society - Perkin Transactions 1, 1996 , # 17 p. 2179 - 2185

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被引用次数: 15

摘要

Different approaches to the synthesis of 1-chloroalkylphosphinates are described. Initially, we tried to extend a reaction described by Kabachnik for the preparation of chloromethylphosphinic acid chlorides [R1 (Cl) P (O) CH2Cl] to C-substituted derivatives. We also considered the possibility of synthesizing the title compounds by routes already described for the formation of diethyl 1-chloroalkylphosphonates. Although these methods ...