Neutral pentacoordinate silicon (IV) complexes with a tridentate dianionic O, N, O or N, N, O ligand, an anionic PhX ligand (X= O, S, Se), and a phenyl group: …
…, C Burschka, R Bertermann, R Tacke
文献索引：Weiss, Joerg; Theis, Bastian; Baus, Johannes A.; Burschka, Christian; Bertermann, Ruediger; Tacke, Reinhold Zeitschrift fur Anorganische und Allgemeine Chemie, 2014 , vol. 640, # 2 p. 300 - 309
Abstract A series of neutral pentacoordinate silicon (IV) complexes with a SiO 3 NC, SiO 2 SNC, SiO 2 SeNC, SiO 2 N 2 C, SiOSN 2 C, or SiOSeN 2 C skeleton was synthesized and structurally characterized by multinuclear NMR spectroscopy in the solid state and in solution and by single-crystal X-ray diffraction. The compounds studied contain a tridentate dianionic O, N, O or N, N, O ligand, an anionic PhX ligand (X= O, S, Se), and a phenyl ...
