Tetrahedron

Solvent effects on the electronic structure of bis (4-dimethylaminodithiobenzyl) nickel [NiII (4-DMAB)] from uv-vis and epr spectra

A Graczyk, E Biak̵owska, A Konarzewski

文献索引：Graczyk, A.; Bialkowska, E.; Konarzewski, A. Tetrahedron, 1982 , vol. 38, # 17 p. 2715 - 2720

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被引用次数: 4

摘要

The UV-VIS and EPR spectra of solutions of NiII (4-DMAB) in 10 solvents with donor number (DN) from 0.1 to 38.81 have been recorded. The changes in the spectra are in terms of a change in symmetry of the NiII (4-DMAB) complex on increase in donor number of the solvent. The symmetry change is from square planar to rhombic bipyramidal with correspoding change in electronic configuration of the nickel ion from d2z2 to d1z2, d1x2- ...