Reactions of β??sulfenyl α, β??unsaturated ketones with guanidine, Amidines, and diamines

T Nishio, T Tokunaga, Y Omote

文献索引：Nishio, Takehiko; Tokunaga, Tatsuhiro; Omote, Yoshimori Journal of Heterocyclic Chemistry, 1985 , vol. 22, p. 405 - 407

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被引用次数: 14

摘要

Abstract β-Sulfenyl α, β-unsaturated ketones 1a-c reacted with guanidine or amidines to give pyrimidine derivatives 3 in 14-76% yields. Treatment of ketones 1 with diamines such as ethylenediamine and o-phenylenediamine afforded the seven-membered heterocycles, 2, 3- dihydro-1, 4-diazepine 5 and 2, 3-benzo-1, 4-diazepines 8a-c.