Cobalt carbonyl catalyzed reactions of esters and lactones with hydrosilane and carbon monoxide. A novel synthetic method for the introduction of the …

N Chatani, S Fujii, Y Yamasaki, S Murai…

文献索引：Chatani,N.; Fujii,S.; Yamasaki,Y. Journal of the American Chemical Society, 1986 , vol. 108, p. 7361

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被引用次数: 30

摘要

Abstract: The catalytic reactions of esters and lactones with hydrosilane and carbon monoxide in the presence of CO,(CO)~ have been studied in detail with the emphasis being focused on their utility in organic synthesis. The catalytic reaction of secondary alkyl acetates underwent clean incorporation of carbon monoxide to give (siloxymethy1idene) alkanes (enol silyl ethers). Lactones of secondary alkyl ester type reacted similarly. The ...