Kinetics of the reaction of the TEMPO radical with alkylarenes

…, AG Matvienko, OZ Bakurova, RA Voloshkin

文献索引：Opeida; Matvienko; Bakurova; Voloshkin Russian Chemical Bulletin, 2003 , vol. 52, # 4 p. 900 - 904

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被引用次数: 2

摘要

Abstract The kinetics of the reaction of the stable radical 2, 2, 6, 6-tetramethylpiperidine-N- oxyl (TEMPO) with a series of alkylarenes containing primary and secondary benzyl C—H bonds was studied by ESR, and the reaction rate constants were determined. The scheme of the process under study was examined, and the applicability boundaries of the simplification during analysis were shown. The selectivities of TEMPO and the more reactive ...