Kinetics of the reaction of the TEMPO radical with alkylarenes

…, AG Matvienko, OZ Bakurova, RA Voloshkin

Index: Opeida; Matvienko; Bakurova; Voloshkin Russian Chemical Bulletin, 2003 , vol. 52, # 4 p. 900 - 904

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Citation Number: 2

Abstract

Abstract The kinetics of the reaction of the stable radical 2, 2, 6, 6-tetramethylpiperidine-N- oxyl (TEMPO) with a series of alkylarenes containing primary and secondary benzyl C—H bonds was studied by ESR, and the reaction rate constants were determined. The scheme of the process under study was examined, and the applicability boundaries of the simplification during analysis were shown. The selectivities of TEMPO and the more reactive ...