Reusable supported ruthenium catalysts for the alkylation of amines by using primary alcohols

…, TT Dang, AM Seayad, B Ramalingam

文献索引：Peishan, Siah; Dang, Tuan Thanh; Seayad, Abdul Majeed; Ramalingam, Balamurugan ChemCatChem, 2014 , vol. 6, # 3 p. 808 - 814

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被引用次数: 2

摘要

Abstract Efficient and recyclable ruthenium catalysts were synthesized from readily available polystyrene-or silica-supported phosphine ligands. Catalysts bound to the polymer support through an ether linkage showed good to excellent activity towards the N-alkylation of primary and secondary amines to afford the alkylated products in 62–99% yield at 120–140 C. The supported phosphine ligand/ruthenium ratio was found to be crucial for higher ...