Journal of the American Chemical Society

The Decarboxylative Acylation of α-Substituted Acids

JA King, FH McMillan

文献索引：King; McMillan Journal of the American Chemical Society, 1955 , vol. 77, p. 2814

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被引用次数: 9

摘要

It has been shown that carboxylic acids having certain electron-withdrawing groups attached to the a-position to the carboxyl group can be made to undergo a decarboxylative acylation reaction in the presence of an acylating agent and a base to give a compound in which the original carboxyl group is replaced by an acyl group. The types of electronwithdrawing groups are varied and there are in all probability at least two major routes by which this ...