Tetrahedron Letters

Co 2 (CO) 8 as a convenient in situ CO source for the direct synthesis of benzamides from aryl halides (Br/I) via aminocarbonylation

P Baburajan, KP Elango

文献索引：Baburajan, Poongavanam; Elango, Kuppanagounder P. Tetrahedron Letters, 2014 , vol. 55, # 5 p. 1006 - 1010

被引用次数: 10

摘要

Abstract A fast, mild, and functional group tolerant method for the direct synthesis of benzamides from aryl halides (Br, I) via aminocarbonylation, using solid Co 2 (CO) 8 as a convenient CO source, has been demonstrated. The developed method is applicable to a wide variety of 1 and cyclic and acyclic 2 amines. Nitro substituted (o, m and p) aryl halides have easily been converted to the corresponding benzamides, without the reduction of the ...

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