Tetrahedron

Palladium catalysed reactions of allenes, carbon monoxide and nucleophiles

R Grigg, M Monteith, V Sridharan, C Terrier

文献索引：Grigg, Ronald; Monteith, Michael; Sridharan, Visuvanathar; Terrier, Catherine Tetrahedron, 1998 , vol. 54, # 15 p. 3885 - 3894

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被引用次数: 44

摘要

Hydridopalladium (II) species generated in situ by oxidative addition of Pd (0) to acetic acid or acidic hydroxyl substrates (phenols, oximes) catalyse the termolecular assembly of allenes, CO and amines (primary, secondary) or oxygen nucleophiles to give methacrylamides or methacrylate esters and derivatives thereof in good to excellent yield.