Synlett

Malononitrile as acylanion equivalent

S Förster, O Tverskoy, G Helmchen

文献索引：Foerster, Sebastian; Tverskoy, Olena; Helmchen, Guenter Synlett, 2008 , # 18 p. 2803 - 2806

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被引用次数: 21

摘要

Abstract The oxidation of derivatives of malononitrile with peracid in methanol proceeds with loss of the cyano groups to yield methyl esters in high yield. The method was applied to a variety of malononitrile derivatives, some of which were prepared by Pd-or Ir-catalyzed asymmetric allylic substitution.