Chemistry Letters

Improved Procedure for Single-electron-transfer-induced Grignard Cross-coupling Reaction

E Shirakawa, K Okura, N Uchiyama, T Murakami…

文献索引：Shirakawa, Eiji; Okura, Keisho; Uchiyama, Nanase; Murakami, Takuya; Hayashi, Tamio Chemistry Letters, 2014 , vol. 43, # 6 p. 922 - 924

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被引用次数: 4

摘要

Aryl Grignard reagents were found to undergo coupling with aryl or alkenyl bromides in the presence of LiCl in a mixed solvent consisting of toluene and THF (2/1). Previously employed removal of THF with evacuation from Grignard solutions is no longer needed to obtain biaryls and styrene derivatives.