Metallomicelles as catalysts of the hydrolysis of carboxylic and phosphoric acid esters

P Scrimin, P Tecilla, U Tonellato

文献索引：Scrimin, Paolo; Tecilla, Paolo; Tonellato, Umberto Journal of Organic Chemistry, 1991 , vol. 56, # 1 p. 161 - 166

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被引用次数: 120

摘要

Results Ligands. Ligands 2 and 3 have been synthesized by reaction of 2-(carboxymethyl)-6- formylpyridine8 with the proper alkylamine followed by reduction with NaBH4. Ligand 4 has been obtained by reduction of the imine formed by reacting 2-formylpyridine with n- dodecylamine. None of them is dispersible in neutral aqueous solutions; nevertheless, in the presence of at least 1 equiv of Cu2+ ions ligands 2 and 3 form clear dispersions at pH= ...