Sonochemistry and sonocatalysis of metal carbonyls

KS Suslick, JW Goodale, PF Schubert…

文献索引：Suslick, Kenneth S.; Goodale, James W.; Schubert, Paul F.; Wang, Hau H. Journal of the American Chemical Society, 1983 , vol. 105, # 18 p. 5781 - 5785

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被引用次数: 157

摘要

Abstract: Ultrasonic irradiation of liquids produces acoustic cavitation: the rapid formation, growth, and implosive collapse of vapor filled vacuoles. This generates short-lived “hot spots” with peak temperatures-3000 K and nanosecond lifetimes. We have studied the effects of high intensity ultrasound on a variety of metal carbonyls and have observed the general phenomenon of sonochemical ligand dissociation, which often produces multiple ...