Inorganic chemistry

Synthesis of Blue Imino (pentafluorophenyl) phosphane

M Kuprat, M Lehmann, A Schulz, A Villinger

文献索引：Kuprat, Marcus; Lehmann, Mathias; Schulz, Axel; Villinger, Alexander Inorganic Chemistry, 2011 , vol. 50, # 12 p. 5784 - 5792

全文：HTML全文

被引用次数: 7

摘要

The reaction of AgC 6 F 5 with monomeric iminophosphanes of Mes*–N═P–X (X = Cl, I) in CH 2 Cl 2 at ambient temperature gives imino(pentafluorophenyl)phosphane, Mes*N═P(C 6 F 5 ) (1), in almost quantitative yield (96%), which could be isolated as a highly viscous blue oil. The same reaction with LiC 6 F 5 results in the formation of imino(amino)phosphane (C 6 F 5 ) 2 P–N(Mes*)–P═NMes* (2) (yield 93%). In the second series of experiments the ...