Electrophilic amination of organozinc reagents with acetone O-(2, 4, 6-trimethylphenylsulfonyl) oxime and O-methylhydroxylamine

E Erdik, T Daşkapan

文献索引：Erdik, Ender; Daskapan, Tahir Journal of the Chemical Society - Perkin Transactions 1, 1999 , # 21 p. 3139 - 3142

全文：HTML全文

被引用次数: 34

摘要

Reaction of diorganozincs and triorganozincates with acetone O-(2, 4, 6- trimethylphenylsulfonyl) oxime or O-methylhydroxylamine in the presence of CuCN provides a new one-flask method for electrophilic amination of organozinc reagents. Considering the lithium-or magnesium-to-zinc transmetallation, this method also extends the scope of electrophilic amination of organolithiums and Grignard reagents.