Ozonolysis of Alkenes and Studies of Reactions of Polyfunctional Compounds: LXV. Ozonolysis of Perfluoro-1-octene in Freon-113

…, VR Akhmetova, MV Bazunova, RG Savchenko…

文献索引：Odinokov; Akhmetova; Bazunova; Savchenko; Paramonov; Khalilov Russian Journal of Organic Chemistry, 2001 , vol. 37, # 3 p. 321 - 325

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被引用次数: 1

摘要

Abstract Ozonization of perfluoro-1-octene in Freon-113 yields the corresponding ozonide whose catalytic hydrogenation over Pd/C or hydride reduction leads to formation of perfluoroheptanoic acid; the reduction with lithium aluminum hydride gives 2, 2, 3, 3, 4, 4, 5, 5, 6, 6, 7, 7, 7-tridecafluoro-1-heptanol. Ozonization of perfluoro-1-octene in Freon-113 containing excess (≥ 3 equiv) alcohol affords the corresponding perfluoroheptanoic acid ...