The Journal of Organic Chemistry

Reaction of triflates with potassium diethyl phosphite. Formation of phosphate esters

X Creary, B Benage, K Hilton

文献索引：Creary, Xavier; Benage, Brigitte; Hilton, Kathryn Journal of Organic Chemistry, 1983 , vol. 48, # 17 p. 2887 - 2891

全文：HTML全文

被引用次数: 19

摘要

Phenyl triflate and substituted analogues react with potassium diethyl phosphite in liquid ammonia to form aryl diethyl phosphate esters. The reaction formally involves loss of trifluoromethanesulfiiate ion from the triflate and concomitant oxidation of phosphorus to the phosphate stage. Preliminary data suggest that, in a series of triflates, reactivity follows the order aryl> cyclohexenyl> cyclopropyl> alkyl. Studies on aryl triflates with added labeled ...