The Structure of Styrene Oxide Dimers. 1 II. Chemical Evidence

RK Summerbell, MJ Kland-English

文献索引：Summerbell; Kland-English Journal of the American Chemical Society, 1955 , vol. 77, p. 5095,5098

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被引用次数: 8

摘要

In the previous paper, 2 the reaction of 2, 5-dichloro-1, 4-dioxane with phenylmagnesium bromide to give two isomeric 2, 5-diphenyl-1, 4-dioxanes (I) was described. However, the proof of structure of the products was not entirely satisfactory, since ether cleavage experiments gave phenylethylen e glycol in yields too low to exclude the possibility of an acetal I1 or ketal I11 structure. Also, hydrogenation experiments of Baker3 and co-workers ...