Preparation of Diethyl 2-Alkoxymethyl-, 2-Phenylselenomethyl-and 2-Phenylthiomethylmalonate

JL Delépine, P Pecquet, M Betton…

文献索引：Delepine, Jean-Louis; Pecquet, Pascal; Betton, Marie-Christine; Huet, Francois Synthetic Communications, 1996 , vol. 26, # 15 p. 2819 - 2829

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被引用次数: 7

摘要

Preparation of dialkyl 2-alkoxymethylmalonates is usually performed by ... In our hands, attempts to prepare compound la by reaction between ... Therefore we carefully examined results according to the experimental conditions. ... Me0 CO2Et EtO2C CO,Et CO2Et 3 4 ... Aco2Et "inverse Et02CCHNaC02Et + ROCH2C1 - 5 conditions" RO CO2Et ... We fustly found that addition of chloromethyl methyl ether to the sodium derivative ... 5 ("direct conditions") in refluxing THF, only led to a ...