Reactions of Diorganyl Disulfides with Dihaloalkanes in Basic Reductive Media. Synthesis of Bis (organylthio) alkanes

OV Alekminskaya, NV Russavskaya…

文献索引：Alekminskaya; Russavskaya; Korchevin; Deryagina Russian Journal of General Chemistry, 2002 , vol. 72, # 1 p. 75 - 78

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被引用次数: 11

摘要

Abstract A convenient preparative synthesis of bis (organylthio) alkanes was developed. It is based on alkylation with dihaloalkanes of solutions of diorganyl disulfides in the basic reductive system hydrazine hydrate-alkali. The generation of organylthiolate anions from disulfides and the subsequent reaction of the anions with dihaloalkanes are performed in one reaction vessel without isolation of intermediate alkali metal thiolates. At the same ...