A New, Mild, General and Efficient Route to Aryl Ethyl Carbonates in Solvent??Free Conditions Promoted by Magnesium Perchlorate

…, E Marcantoni, P Melchiorre, P Palazzi…

文献索引：Bartoli, Giuseppe; Bosco, Marcella; Carlone, Armando; Locatelli, Manuela; Marcantoni, Enrico; Melchiorre, Paolo; Palazzi, Paolo; Sambri, Letizia European Journal of Organic Chemistry, 2006 , # 19 p. 4429 - 4434

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被引用次数: 7

摘要

Abstract A new, general and mild method for the direct synthesis of aryl and alkyl ethyl carbonates promoted by a Lewis acid is reported. The reaction proceeds smoothly with diethyl dicarbonate in the presence of Mg (ClO 4) 2, a specific activator of 1, 3-dicarbonyl compounds, and shows general applicability.(© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2006)