Déplacements homolytiques intramoléculaires. 2. Décomposition du perpentène-4 oate de tert-butyle dans les éthers

A Kharrat, C Gardrat, B Maillard

文献索引：Kharrat, A.; Gardrat, C.; Maillard, B. Canadian Journal of Chemistry, 1984 , vol. 62, p. 2385 - 2390

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被引用次数: 9

摘要

The thermolysis of tert-butyl perpent-4-enoate 1 in THF led to several compounds; the main product, 5-(2-tetrahydrofuryl)-4-pentanolide (yield 42%) comes from an induced decomposition of the perester occurring with the addition of 2-tetrahydrofuryl radical to the double bond. A similar reaction was performed at a lower temperature, using butyl perdicarbonate as initiator, but did not define the mechanism (concerted or two-step). The ...