Synthese et étude structurale d'acides alkylphosphoniques à longue chaine hydrocarbonée

M Gaboyard, Y Hervaud, B Boutevin

文献索引：Gaboyard; Hervaud; Boutevin Phosphorus, Sulfur and Silicon and Related Elements, 2002 , vol. 177, # 4 p. 877 - 891

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被引用次数: 15

摘要

Long-chain dialkyl alkylphosphonates were synthesized by radical addition of dialkyl hydrogenphosphonates onto alkenes in presence of di (t-butyl) peroxide. This synthetic route leads to high yields between 94 and 97%. We performed chemical modifications of these phosphonates in order to obtain acidic derivatives. The structure of these compounds was characterized by NMR analyses and mass spectroscopy. We also studied their ...