The Journal of Organic Chemistry

The Thermal Reaction between Alkylating Agents and Phosphonate or Phosphate Esters

RG LAUGHLIN

文献索引：Laughlin,R.G. Journal of Organic Chemistry, 1962 , vol. 27, p. 1005 - 1011

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被引用次数: 5

摘要

RESULTS In this paper it is shown that O-alkyl groups of simple aliphatic phosphonate or phosphate esters react with suitable alkylating agents to undergo an alkyl exchange reaction at high temperatures. This reaction has proved to be a useful synthesis of mixed esters of phosphonio or phosphoric acids, and has also been shown to occur as a si& reaction in certain Michaelis-Arbuzov reactions. Although Harwood and Grisley 'a were ...