The intramolecular silyl-modified Sakurai (ISMS) reaction. A simple and versatile synthesis of tetrahydropyrans, spiro ethers, and spiro ketals

…, A Mekhalfia, DJ Bayston, H Adams

文献索引：Marko, Istvan E.; Mekhalfia, Abdelaziz; Bayston, Daniel J.; Adams, Harry Journal of Organic Chemistry, 1992 , vol. 57, # 8 p. 2211 - 2213

全文：HTML全文

被引用次数: 62

摘要

Summary: The Intramolecular Silyl Modified Sakurai (ISMS) reaction is a powerful tool for the construction of tetrahydropyrans, spiroethers, and spiroketals. The ISMS methodology was applied to a short and stereocontrolled synthesis of a minor component of the rectal gland secretion of the female Daws oleae fruit fly.