Reactions of nucleophilic substitution involving solid organic halogen compounds under shear deformation at high pressure

…, NP Chistotina, RG Gaziev, II Yakovleva

文献索引：Zharov, A. A.; Chistotina, N. P.; Gaziev, R. G.; Yakovleva, I. I. Russian Chemical Bulletin, 1995 , vol. 44, # 6 p. 1050 - 1055 Izvestiya Akademi Nauk, Seriya Khimicheskaya, 1995 , # 6 p. 1090 - 1095

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摘要

Abstract Under conditions of shear deformation and high pressures (SD+ HP), reactions of nucleophilic substitution were studied: 1) the replacement of aliphatic halogen atom with alkaline metal halides (halo-substituted aliphatic carboxylic acids, 1-bromoadamantane); 2) the replacement of halogen atom in aromatic nucleus (halobenzoic acids, dihalobenzenes) with halogen of salt; 3) the replacement of aliphatic halogen with hydroxyl (hydrolysis in a ...