Tetrahedron: Asymmetry

Asymmetric cyanohydrin formation from aldehydes catalyzed by manganese Schiff base complexes

Y Qu, L Jing, Z Wu, D Wu, X Zhou

文献索引：Qu, Yanyang; Jing, Linhai; Wu, Zhiqing; Wu, Di; Zhou, Xiangge Tetrahedron Asymmetry, 2010 , vol. 21, # 2 p. 187 - 190

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被引用次数: 10

摘要

The cyanohydrin formation reaction is one of the fundamental carbon–carbon bond-forming reactions in organic chemistry. 1 Optical cyanohydrins can usually be used as versatile synthons to form a wide variety of important chiral compounds such as α-amino acids, α-hydroxy carboxylic acids, β-amino alcohols, vicinal diols and α-hydroxy ketones. 2 In the last few decades, a range of catalysts has been developed for this reaction including enzymes, 3 cyclic dipeptides, 4 ...