Tetrahedron Letters

Synthesis of dialkyl and diaryl benzylphosphonates through a ZnI 2-mediated reaction

RM Richardson, RJ Barney, DF Wiemer

文献索引：Richardson, Rebekah M.; Barney, Rocky J.; Wiemer, David F. Tetrahedron Letters, 2012 , vol. 53, # 49 p. 6682 - 6684

全文：HTML全文

被引用次数: 4

摘要

Several trialkyl and two triaryl phosphites have been tested for their reactivity in the zinc iodide mediated conversion of benzyl alcohol to the corresponding phosphonates. Most react smoothly to afford the desired phosphonate diesters, including hindered and nonracemic phosphites. The implications of this reactivity on the reactions involved in the transformation are discussed.