Photo-Arbuzov rearrangements of benzyl phosphites

…, K Akutagawa, SM Cairns, WG Bentrude

文献索引：Omelanzcuk, Jan; Sopchik, Alan E.; Lee, Sueg-Geun; Akutagawa, Kunihiko; Cairns, Matthew S.; Bentrude, Wesley G. Journal of the American Chemical Society, 1988 , vol. 110, # 20 p. 6908 - 6909

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被引用次数: 25

摘要

The thermal Arbuzov rearrangement is a widely known'reaction of organophosphorus molecules, eq 1. It classically occurs via a two-step mechanism catalyzed by RX (X= halide, tosylate, etc.) and in certain instances can be autocatalytic. lc Intermolecular free-radical Arbuzov reactions are known as wells2