Metal-catalyzed organic photoreactions. Bond-cleavage selectivity and synthetic application of the iron (III) chloride catalyzed photooxidation of cyclic olefins

A Kohda, K Nagayoshi, K Maemoto…

文献索引：Kohda, Akira; Nagayoshi, Kazuo; Maemoto, Kazuo; Sato, Tadashi Journal of Organic Chemistry, 1983 , vol. 48, # 4 p. 425 - 432

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被引用次数: 21

摘要

Photooxidation of olefins in pyridine in the presence of iron (II1) chloride produced either a- chloro ketones (type A), gem-dichloro ketones (type B), or a, w-dichloro ketones (type C), depending upon the substitution pattern of the substrate olefin. The synthetic utility of the type B reaction was demonstrated by the synthesis of some natural products. The synthesis of optically active solanone from Dp-menthene confirmed the D configuration of the ...