The photochemical rearrangement of 1, 2??dihydronaphthalenes into 1, 4??dihydronaphthalenes induced by amines

…, N Berendsen, WH Laarhoven

文献索引：Cuppen, Th. J. H. M.; Berendsen, N.; Laarhoven, W. H. Recueil des Travaux Chimiques des Pays-Bas, 1990 , vol. 109, # 3 p. 168 - 171

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摘要

Abstract The synthetic usefulness of the deprotonation/protonation reaction of excited 1, 2- dihydronaphthalenes into 1, 4-dihydronaphthalenes induced by amines has been investigated using 13 different substituted 1, 2-dihydronaphthalenes and related compounds. The yield of the rearrangement ranges from 5 to 96%. The formation of side- products depends on the position of protons in the substrate, which can be abstracted by ...

4373-13-1

4-甲基-1,2-二氢萘

~4%

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~5%

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~43%

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~46%

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~1%

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~20%

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~66%

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~46%

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~52%

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~12%

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~9%

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~16%

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