Application of the Savage-Wood treatment to the quantitative analysis of kinetic solvent effects in highly aqueous binary solutions

…, J Jager, JBFN Engberts, MJ Blandamer

文献索引：Blokzijl, Wilfried; Jager, Jan; Engberts, Jan B. F. N.; Blandamer, Michael J. Journal of the American Chemical Society, 1986 , vol. 108, # 20 p. 6411 - 6413

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被引用次数: 37

摘要

In (kobsd/kabsdo)= In YS-In 71-n $ ImAMI(2) where ys and yt are the activity coefficients of the I-acyl-1, 2, 4-triazole (S) and transition state (*), respectively, n is the molecularity of the hydrolysis reaction with respect to water (n= 2 for 2), $ I is the practical osmotic coefficient for the solution, and MI is the molar mass of water. 6 In the binary mixture ys is to the Gibbs function substrate-alcohol pairwise interaction parameters gAS and gss via