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Canadian Journal of Chemistry

Bicyclo [2, 2, 1] heptylphosphonates II. Stéréochimie de l'addition de Diels-Alder du vinylphosphonate de diméthyle sur quelques cyclopentadiènes; étude par …

HJ Callot, C Benezra

文献索引:Callot,H.J.; Benezra,C. Canadian Journal of Chemistry, 1970 , vol. 48, p. 3382 - 3387

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被引用次数: 15

摘要

The stereochemistry of the Diels-Alder addition of the vinylphosphonate (1) to cyclopentadiene, hexachlorocyclopentadiene (6), dimethoxytetrachlorocyclopentadiene (8), and pentachlorocyclopentadiene (10) has been studied. The configuration of the compounds has been proved by chemical correlation and essentially by nmr spectroscopy. The study of the nmr spectra confirms the 31P, 1H vicinal coupling dihedral angular ...