Canadian Journal of Chemistry

Bicyclo [2, 2, 1] heptylphosphonates II. Stéréochimie de l'addition de Diels-Alder du vinylphosphonate de diméthyle sur quelques cyclopentadiènes; étude par …

HJ Callot, C Benezra

Index: Callot,H.J.; Benezra,C. Canadian Journal of Chemistry, 1970 , vol. 48, p. 3382 - 3387

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Citation Number: 15

Abstract

The stereochemistry of the Diels-Alder addition of the vinylphosphonate (1) to cyclopentadiene, hexachlorocyclopentadiene (6), dimethoxytetrachlorocyclopentadiene (8), and pentachlorocyclopentadiene (10) has been studied. The configuration of the compounds has been proved by chemical correlation and essentially by nmr spectroscopy. The study of the nmr spectra confirms the 31P, 1H vicinal coupling dihedral angular ...