Journal of the Chemical Society (Resumed)

639. Reactions of fluorocarbon radicals. Part XI. Synthesis and some reactions of trifluoromethanethiol and trifluoromethanesulphenyl chloride

RN Haszeldine, JM Kidu

文献索引：Haszeldine; Kidd Journal of the Chemical Society, 1953 , p. 3219,3225

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被引用次数: 39

摘要

CF,-S-SS* CF,+ CF,. SCF3+ CF,. S. SCF,+ CF,* S-CF,+ S The reaction of trifluoroiodomethane with sulphur is best carried out in an autoclave at 310, since the yield of bistrifluoromethyl disulpbide is then high (75y0), and the formation of carbon disulphide