A new facile route to primary alkanenitriles from terminal alkenes via a hydroboration–cyanation sequence

Y Masuda, M Hoshi, A Arase

文献索引：Masuda, Yuzuru; Hoshi, Masayuki; Arase, Akira Journal of the Chemical Society, Chemical Communications, 1989 , # 5 p. 266 - 267

全文：HTML全文

被引用次数: 0

摘要

Although some methods for the synthesis of alkanenitriles by two- or more-carbon homologation of organoborane have been reported,la synthesis of secondary alkanenitrile from trialkylcyanoborate,2 reported previously by us, seemed to be a potentially useful method for the conversion of internal alkenes to the corresponding one-carbon homologated secon- dary alkanenitriles.3 However, an attempt to obtain primary alkanenitriles from terminal ...