Advanced Synthesis & Catalysis

A Simple Synthetic Route to Enantiopure α??Hydroxy Ketone Derivatives by Asymmetric Hydrogenation

T Sun, X Zhang

文献索引：Sun, Tian; Zhang, Xumu Advanced Synthesis and Catalysis, 2012 , vol. 354, # 17 p. 3211 - 3215

被引用次数: 7

摘要

Abstract High enantioselectivities (up to 99% ee) have been observed for the catalytic asymmetric hydrogenation of the α-ketone enol acetates. DuanPhos has been proved to be the most effective ligand for this reaction. The high yield and enantioselectivity of the

~92%

~87%

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[Sun, Tian; Hou, Guohua; Ma, Miaofeng; Zhang, Xumu Advanced Synthesis and Catalysis, 2011 , vol. 353, # 2-3 p. 253 - 256]