The Journal of Organic Chemistry

Formation of cage-structure organomagnesium compounds. Influence of the degree of adsorption of the transient species at the metal surface

G Molle, P Bauer, JE Dubois

文献索引：Molle, G.; Bauer, P.; Dubois, J. E. Journal of Organic Chemistry, 1982 , vol. 47, # 21 p. 4120 - 4128

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被引用次数: 59

摘要

Secondary and tertiary adamantyl organomagnesium compounds have been synthesized with yields of ca. 60% by means of an original static procedure. By condensing Grignard reagents of adamantane over benzaldehyde, 70% and 72% yields of alcohol are obtained; the 1-and 2-adamantanecarboxylic acid chlorides give 40% and 50% yields of 1, l-and 2, 2- diadamantyl ketone, respectively. Competition between the various reactions occurring ...