Carbonion (ElcB) mechanism of ester hydrolysis. I. Hydrolysis of malonate esters

B Holmquist, TC Bruice

文献索引：Journal of the American Chemical Society, , vol. 91, p. 2993 - 3002

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被引用次数: 44

摘要

... All nucleophiles studied in the reaction with ester V gave linear plots of kobsd us. [Nf] from whose slopes was calculated kz (Table 11). ... kobsd - khydr = kz'[N~l[K,/(& d- OH)] = MNf] Journal of the American Chemical Society 91:11 / May 21, 1969 Page 5. 2997 Table III. ...