Metal catalysis in oxidation by peroxides. Part 33. Chemoselective alcohol oxidations by the anionic molybdenum-picolinate N-oxido peroxo complex MoO5PICO

S Campestrini, F Di Furia, G Modena…

文献索引：Campestrini, Sandro; Furia, Fulvio Di; Modena, Giorgio Journal of Organic Chemistry, 1990 , vol. 55, # 11 p. 3658 - 3660

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被引用次数: 24

摘要

Both peroxogroups of Mo0, PICO react with primary and secondary alcohols in nonpolar solvents under mild conditions to give high yields of aldehydes and ketones, respectively. 2 Although there are several procedures for alcohol oxidation^,^ including recent Mo0, PICO may be considered to be of particular synthetic interest because it allows for the oxidation of a primary alcoholic function to aldehyde without overoxidation to the carboxylic a~ id.~~'? ...