Heterocycles

New synthetic approach to 1-azabicyclo [xy 0] alkane skeletons from β-enamino diesters derived from Meldrum's acid

…, JP Célérier, G Haviari, G Lhommet, H Dhimane…

文献索引：Haddad, Mansour; Celerier, Jean Pierre; Haviari, Gjergj; Lhommet, Gerard; Dhimane, Hamid; at al. Heterocycles, 1990 , vol. 31, # 7 p. 1251 - 1260

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被引用次数: 12

摘要

Résumé/Abstract Two complementary methods for the synthesis of title compounds, namely, monodecarboxylating transesterification of β-enamino esters (I) followed by intramolecular cyclization, and direct cyclization of I under flash vacuum thermolysis conditions, have been elaborated. Azabicyclic compounds were stereospecifically converted to bicyclic β-amino alcohols by means of stereocontrolled carbon-carbon double bond catalytic ...