Self??Assembly and Dynamics of [2]??and [3] Rotaxanes with a Dinuclear Macrocycle Containing Reversible Os− N Coordinate Bonds

SY Chang, JS Choi, KS Jeong

文献索引：Chang, Sung-Youn; Choi, Jeung Soon; Jeong, Kyu-Sung Chemistry - A European Journal, 2001 , vol. 7, # 12 p. 2687 - 2697

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被引用次数: 45

摘要

Abstract With a dinuclear macrocycle 2 that contains weak reversible Os VI− N coordinate bonds, self-assembly and equilibrium dynamics of [2]-and [3] rotaxanes have been investigated. When the macrocycle 2 was mixed together with threads 4 a–e, which all contain an adipamide station but different sizes of end groups,[2] pseudorotaxane-and rotaxane-like complexes were immediately formed with large association constants of> 7× ...